Dunno about ethanol-fuelled cars, that's not really my area - it sounds like a great idea though.
Not that ZPE or cold fusion really *are* my areas, but I say they can't be used for free energy because I think the science itself is unsound. With an ethanol car you're still just burning a hydrocarbon in some kind of internal combustion engine (I assume), so whether it works or not is going to be down to nitty-gritty engineering details. ZPE, in our current understanding, is a non-starter *on principle* - it doesn't even get off the blackboard.
Hydrogen fuel cells could be very big though, as long as the storage technology is efficient and safe enough. That's about the only way electric cars are going to be worthwhile. Still, you have to get the electricity from somewhere, so whether it's a 'green' technology or not depends entirely on your power source.